4.7 Article

Manganese(III)-Mediated Selective Diphenylphosphinoyl Radical Reaction of 1,4-Diaryl-1-butynes for the Synthesis of 2-Phosphinoylated 3,4-Dihydronaphathalenes

Journal

JOURNAL OF ORGANIC CHEMISTRY
Volume 79, Issue 4, Pages 1850-1855

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jo402556a

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Funding

  1. National Natural Science Foundation of China [20772088, 21172163]
  2. Priority Academic Program Development of Jiangsu Higher Education Institutions

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A diphenylphosphinoyl radical-initiated sequential reaction of 1,4-diaryl-1-butynes and analogues is developed for the synthesis of 2-phosphinoylated 3,4-dihydronaphathalenes and related compounds.

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