Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 79, Issue 19, Pages 9262-9271Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo501709f
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Funding
- Basic Science Research Program through the National Research Foundation of Korea [2013R1A2A2A01005249, 2013R1A1A2058800]
- National Research Foundation of Korea [2013R1A1A2058800] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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A ketone-assisted ruthenium-catalyzed selective amination of xanthones and chromones CH bonds with sulfonyl azides is described. The reactions proceed efficiently with a broad range of substrates with excellent functional group compatibility. This protocol provides direct access to 1-aminoxanthones, 5-aminochromones, and 5-aminoflavonoid derivatives known to exhibit potent anticancer activity.
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