4.7 Article

Accessing Near-Infrared-Absorbing BF2-Azadipyrromethenes via a Push-Pull Effect

Journal

JOURNAL OF ORGANIC CHEMISTRY
Volume 79, Issue 4, Pages 1830-1835

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jo402160b

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Funding

  1. National Nature Science Foundation of China [21072005, 21272007, 21372011]
  2. National Science Foundation of Anhui Province [1208085MB29]
  3. United States National Science Foundation [CHE-0911629]

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Novel aza-BODIPYs with significant bathochromic shifts were designed and synthesized by installation of strong electron-withdrawing groups on the para-positions of 1,7-phenyls and electron-donating groups on the para-positions of 3,4-phenyls. These dyes show strong NIR fluorescence emissions up to 756 nm, and absorptions up to 720 nm.

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