Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 79, Issue 18, Pages 8900-8905Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo501544h
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Funding
- National NSFC [21202065]
- Natural Science Foundation of Jiangxi Province [20142BAB213004]
- Specialized Research Fund for the Doctoral Program of Higher Education [20123604120003]
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Here, we report on an efficient palladium/norbornene-catalyzed domino reaction of aryl halide, O-acyl hydroxylamine (R1R2N-OBz), and aromatic pinacol boronate (R-Bpin), selectively affording a series of biaryl tertiary amines in good to high yields with excellent functional group tolerance. This catalytic reaction provides a new opportunity for the convergent synthesis of biaryl amines from easily accessible starting materials.
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