Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 79, Issue 2, Pages 777-782Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo402084m
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Funding
- National Science Foundation of China [21072022, 21242006, 21372031]
- Specialized Research Fund for the Doctoral Program of Higher Education [20100003110010]
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An unexpectedly facile synthetic approach for symmetrical and unsymmetrical 2,2'-bipyridines through the Ni-catalyzed reductive couplings of 2-halopyridines was developed. The couplings were efficiently catalyzed by 5 mol % of NiCl2 center dot 6H(2)O without the use of external ligands. A variety of 2,2'-bipyridines including caerulomycin F have been efficiently synthesized.
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