Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 79, Issue 13, Pages 6366-6371Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo5009838
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Funding
- Ministry of Education, Culture, Sports, Science, and Technology of Japan (MEXT)
- Grants-in-Aid for Scientific Research [26288051, 23246013, 25105702, 25670049] Funding Source: KAKEN
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A sulfur-modified gold-supported palladium material (SAPd) has been developed bearing palladium nanoparticles on its surface. Herein, we report for the first time the use of SAPd to affect a Pd-nanoparticle-catalyzed 1,7-Pd migration reaction for the synthesis of benzotriazoles via C-H bond activation. The resulting benzotriazoles were evaluated in terms of their inhibitory activity toward indoleamine 2,3-dioxygenase.
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