Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 79, Issue 7, Pages 3200-3205Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo4028825
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Funding
- National Natural Science Foundation of China [21272117, 20972068]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
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This note describes the efficient and highly regioselective synthesis of 2-(2'-alkenylphenyl)phenol derivatives via palladium-catalyzed 2'-alkenylation of 2-arylphenols directed by the phenolic hydroxyl group using benzoquinone as the oxidant in an atmosphere of air. This reaction can tolerate a series of functional groups and provides the alkenylation products regio- and stereoselectively in moderate to good yields.
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