Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 79, Issue 5, Pages 2314-2320Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo500063r
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- Graduate School of Molecular Science
- Deutsche Forschungsgemeinschaft (DFG)
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Substituted 2-aminobiphenyls have been prepared from arylhydrazine hydrochlorides and anilines in biphasic radical arylation reactions with dioxygen from air as a most simple and readily available oxidant. Under optimized conditions, the free amino functionality of the aniline leads to high ortho:meta regioselectivities, now even for anilines bearing a donor substituent in the para position. Finally, the mild and metal-free new access to aminobiphenyls was shown to be applicable on a gram scale.
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