Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 79, Issue 5, Pages 2213-2225Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo500076c
Keywords
-
Categories
Funding
- Ministerio de Economia y Competitividad, Spain [CTQ2012-31611]
- Junta de Castilla y Leon
- Consejeria de Educacion y Cultura y Fondo Social Europeo [BU246A12-1]
- European Commission [SNIFFER FP7-SEC-2012-312411]
Ask authors/readers for more resources
The scandium triflate-catalyzed cycloaddition reaction of polycyclic 1,2-dithiolethiones to maleimides is described. The reaction constitutes an easy approach to linear as well as branched oligomeric cis-fused dihydro [1,3]dithiolo[4,5-c]pyrrole-4,6-dione rings interconnected by 3,5-diylidenethiomorpholine-2,6-dithione or ylidene-6-thioxo[1,2]dithiolo[3,4-b][1,4]thiazin-3-one groups. The presence of highly colored, highly polarized push pull alpha,beta-unsaturated thione groups in their structures make these compounds sensitive to the presence of mercury(II) cation in organic or mixed organic/aqueous solvents.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available