Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 78, Issue 22, Pages 11366-11372Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo401915t
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Funding
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
- NSFC [21072142, 21272165]
- National Natural Science Foundation of China [21104064]
- Natural Science Foundation of Jiangsu Normal University [10XLR03]
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An iodide-catalyzed process to synthesize N-nitrosamines has been developed using TBHP as the oxidant. The mild catalytic system succeeded in cleaving the carbon-nitrogen bond in nitromethane. This methodology uses commercially available, inexpensive catalysts and oxidants and has a wide substrate scope and operational simplicity.
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