Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 79, Issue 1, Pages 452-458Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo402539p
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Funding
- National Institutes of Health [GM-49093, P41 GM089164]
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Protected 4-hydroxycyclopentenones (4-HCPs) constitute an important class of intermediates in chemical synthesis. A route to this class of compound has been developed. Key steps include Noyori reduction (which establishes the stereochemistry of the product), ring-closing metathesis, and simple functional group conversions to provide a set of substituted 4-HCPs in either enantiomeric form.
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