Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 78, Issue 24, Pages 12314-12320Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo4017953
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Funding
- California Institute of Technology
- NIH [NIGMS RGM097582A]
- Baxter Foundation
- Amgen
- Boehringer Ingelheim
- ACS Petroleum Research Foundation
- ACS Division of Organic Chemistry sponsored by Genentech
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Pyrroloindoline alkaloids constitute a large family of natural products that has inspired the development of an impressive array of new reactions to prepare the key heterocyclic motif. This synopsis will address catalytic, asymmetric reactions developed to synthesize pyrroloindolines bearing C3a all-carbon quaternary stereocenters. The methods described herein include both transition-metal-catalyzed and organocatalyzed reactions that have been demonstrated to be suitable for the synthesis of the pyrroloindoline framework.
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