Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 78, Issue 7, Pages 2813-2818Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo4002239
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Funding
- ACS Division of Organic Chemistry
- University of Utah Graduate School
- National Science Foundation [CHE-1110599]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1110599] Funding Source: National Science Foundation
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A classic strategy of physical organic chemists is to probe reaction mechanisms using linear free energy relationships. Identifying such relationships in asymmetric catalytic reactions provides substantial insight into the key factors controlling enantioselectivity, which in turn increases the predictability and applicability of these reactions. The focus of this JOCSynopsis is to highlight several recent examples in which various parameters were identified and applied to the elucidation of LFERs.
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