Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 78, Issue 8, Pages 4145-4152Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo400658d
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Funding
- CaSuS Ph.D. program
- DAAD
- European Research Council under the European Community/ERC [307535]
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The well-characterized ruthenium(II) biscarboxylate complex [Ru(O(2)CMes)(2)(p-cymene)] enabled versatile direct (hetero)arylations of C(sp(3))-H bonds with low (co)catalyst loading and ample substrate scope. Detailed mechanistic studies provided strong support for a facile and reversible C(sp(3))-H bond metalation.
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