Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 78, Issue 16, Pages 8176-8183Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo4012199
Keywords
-
Categories
Funding
- Chinese National Natural Science Foundation [21173178, 21232005]
- National Basic Research Program of China [2012CB821600]
- NFFTBS [J1210014]
- Program for Changjiang Scholars and Innovative Research Team in University
- Collaborative Innovation Center of Chemistry for Energy Materials
Ask authors/readers for more resources
A new method for copper-catalyzed P-C bond formation through reaction of phosphorus nucleophiles with diaryliodonium salts at room temperature is described. Most target products are obtained with this method in high yields within a short reaction time of 10 min. It can be easily adapted to large-scale preparations. When unsymmetrical iodonium salts are employed, nucleophilic substitution occurs preferentially on the sterically hindered aromatic ring or the more electron-deficient ring.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available