4.7 Article

Cross-Coupling of ArX with ArMgBr Catalyzed by N-Heterocyclic Carbene-Based Nickel Complexes

Journal

JOURNAL OF ORGANIC CHEMISTRY
Volume 78, Issue 3, Pages 1054-1061

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jo302425x

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Funding

  1. National Basic Research Program of China [2009CB825300]
  2. National Natural Science Foundation of China [21172208]

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N-Heterocyclic carbene-based pincer nickel complexes were synthesized and characterized. These complexes efficiently catalyze cross-coupling of aryl Grignard reagents with aryl chlorides or fluorides under mild conditions.

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