Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 78, Issue 22, Pages 11508-11512Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo4020744
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Funding
- Ministero dell'Istruzione, dell'Universita e della Ricerca (MIUR) [PRIN 2010CX2TLM]
- Consiglio Nazionale delle Ricerche (CNR)
- Dipartimento di Chimica, Sapienza Universita di Roma, through the Supporting Research Initiative
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The catalytic activity and the selectivity of the new bipyrrolidine-based Fe(II) complexes 2 center dot Fe(OTf)(2) and 3 center dot Fe(OTf)(2) in the oxidation of a series of alkyl and alkenyl hydrocarbons as well as of an aromatic sulfide with H2O2 were tested and compared with the catalytic efficiency of White's parent complex 1 center dot Fe(OTf)(2) in order to evaluate the sensitivity of the reaction to electronic effects.
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