Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 78, Issue 3, Pages 1062-1069Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo302470v
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Funding
- NSFC/RGC Joint Research Scheme [21061160494, N_CUHK467/10]
- UGC [AoE/P-03/08]
- NSFC [20972060, 21190034, 21272098]
- The Program for Changjiang Scholars and Innovative Research Team in University [PCSIRT: IRT1138]
- 111 Project
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Based on a regioselective tris-formylation of a tribenzotriquinacene (TBTQ) hydrocarbon, the racemic C-3-symmetrical TBTQ-trialdehyde and the corresponding TBTQ-trimethanol were synthesized along with their C-1-isomers. Conversion of the C-3-trialdehyde to three diastereomeric TBTQ-based cryptophanes occurring in high yield enabled the preparation of the optically pure C-3-symmetrical TBTQ-trialdehydes and the determination of their absolute configuration. The racemic C-3-symmetrical TBTQ-trimethanol was found to form several stable nanotubular aggregates in the solid state.
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