Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 79, Issue 2, Pages 814-817Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo402457x
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- Alexander von Humboldt Foundation
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Light-induced Brook rearrangements of acylsilanes facilitate silylacylation reactions of electron-deficient internal alkynes. A wide range of aromatic substituents on the acylsilane aryl group are tolerated, affording a series of functionalized enonyl silanes. The presence of electron-withdrawing substituents on the alkyne is crucial for the success of the addition process.
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