Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 78, Issue 8, Pages 3867-3878Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo400287a
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- DST, India
- IIT-Kanpur
- CSIR, India
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A practical approach for the synthesis of 3-substituted indolines via regio- and stereoselective S(N)2-type ring opening of 2-(2-halophenyl)-N-tosylaziridines with heteroatomic nucleophiles (O, N, and S) followed by palladium catalyzed intramolecular C-N cyclization is reported in excellent yields (up to >99%) and enantiomeric excess (ee 99%)
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