Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 78, Issue 12, Pages 5949-5954Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo400598p
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- DST, India
- CSIR-India
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Ferric nitrate with catalytic TEMPO has been identified as a useful reagent for regio- and stereoselective nitration of a wide variety of aromatic, aliphatic, and heteroaromatic olefins. This reaction provided nitroolefins in preparatively useful yields with excellent E-selectivity. Due to its mild nature and operational simplicity, the present protocol is expected to find application in synthetic setup.
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