4.7 Article

Rhodium(III)-Catalyzed Azacycle-Directed Intermolecular Insertion of Arene C-H Bonds into α-Diazocarbonyl Compounds

Journal

JOURNAL OF ORGANIC CHEMISTRY
Volume 78, Issue 11, Pages 5444-5452

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jo400572h

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Funding

  1. National Basic Research Program of China [2010CB833300]
  2. National Natural Science Foundation of China [21172218, 21072188]

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Cp*Rh(III)-catalyzed intermolecular C C couplings between activated alpha-diazocarbonyl compounds and arenes bearing a range of azacyclic directing groups have been achieved. This catalytic alkylation reaction operates under mild conditions with good functional group tolerance.

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