4.7 Article

Cu-Catalyzed Synthesis of Diaryl Thioethers and S-Cycles by Reaction of Aryl Iodides with Carbon Disulfide in the Presence of DBU

Journal

JOURNAL OF ORGANIC CHEMISTRY
Volume 78, Issue 10, Pages 5001-5006

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jo400709s

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Funding

  1. National Natural Science Foundation of China [21032004, 21272132]
  2. National Key Basic Research Program of China (973 program) [2012CB933402]

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Diaryl thioethers and S-cycles were obtained on the basis of the copper-catalyzed reaction of carbon disulfide and aryl iodides in the presence of DBU. This reaction enables the one-pot synthesis of diaryl thioethers by employing cheap, available, and easy-to-handle carbon disulfide with aryl iodides. The reaction was successfully employed in the construction of sulfur-containing cyclic molecules.

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