Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 78, Issue 20, Pages 10421-10426Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo401851m
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Funding
- National Natural Science Foundation of China [21172060]
- Specialized Research Fund for the Doctoral Program of Higher Education [20120161110041]
- Hunan Provincial Natural Science Foundation of China [13JJ2018]
- Hunan Provincial Innovation Foundation for Postgraduate [CX2010B219]
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A novel palladium-catalyzed methylation protocol for the synthesis of methyl-functionalized internal alkynes has been established. This methylation method is achieved through a C(sp)-C(sp(3)) bond formation process and represents a new synthetic application of sulfonium ylides.
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