4.7 Article

Synthesis of Alkyl Hydroperoxides via Alkylation of gem-Dihydroperoxides

Journal

JOURNAL OF ORGANIC CHEMISTRY
Volume 78, Issue 7, Pages 3452-3456

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jo4001564

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Funding

  1. NSF [CHE-1057982]
  2. NIH [RR016544]
  3. Direct For Mathematical & Physical Scien
  4. Division Of Chemistry [1057982] Funding Source: National Science Foundation

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2-Fold alkylation of 1,1-dihydroperoxides, followed by hydrolysis of the resulting bisperoxyacetals, provides a convenient method for synthesis of primary and secondary alkyl hydroperoxides.

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