Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 78, Issue 23, Pages 12128-12135Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo402151g
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Funding
- Sumitomo Foundation
- Grants-in-Aid for Scientific Research [24590147] Funding Source: KAKEN
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A novel and efficient method for the Au(III)/TPPMS-catalyzed direct substitution reaction of benzhydryl and benzylic alcohols with indoles in water is developed. Au(III)/TPPMS is an effective catalyst for the benzylation of the strong pi nucleophile 1-methylindole, while common Bronsted or Lewis acids are ineffective.
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