Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 77, Issue 6, Pages 2878-2884Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo300100x
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Funding
- National Natural Science Foundation of China [20802015, 21072040, 21071040]
- Chinese Ministry of Education
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In this work, an efficient CuSO4-catalyzed S-arylation of thiols with aryl and heteroaryl boronic acids at room temperature is established. This catalytic system can an tolerate a wide variety of thiols and arylboronic acids in the presence of only 5 mol % of CuSO4 as the catalyst and inexpensive 1,10-phen center dot H2O as the ligand. Moreover, this catalytic system used environment-friendly solvent (EtOH) and oxidant (oxygen).
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