Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 77, Issue 24, Pages 11383-11387Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo3022346
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Funding
- National Research Foundation of Korea (NRF) [NRF-2011-0013118]
- National Research Foundation of Korea [2011-0013118] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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A method for trifluoromethylation of alkenes has been developed employing visible light photoredox catalysis with CF3I, Ru(Phen)(3)Cl-2, and DBU. This process works especially well for terminal alkenes to give alkenyl-CF3 products with only E-stereochemistry. The mild reaction conditions enable the trifluoromethylation of a range of alkenes that bear various functional groups.
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