Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 77, Issue 7, Pages 3426-3432Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo300016a
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Funding
- NSFC [91027005, 21132005]
- Shanghai Shuguang Program [09SG25]
- SMEC [10ZZ32]
- RFDP of Higher Education of China [20100076110004]
- Fundamental Research Funds for the Central Universities
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A new family of 60 degrees dendritic di-Pt(II) acceptor tectons have been successfully designed and synthesized, from which a series of novel threecomponent triangular metallodendrimers were prepared via [3 + 3] coordination-driven self-assembly. The structures of newly designed triangular metallodendrimers are characterized by multinuclear NMR (H-1 and P-31), H-1 DOSY NMR, mass spectrometry (CSI-TOF-MS), and elemental analysis. The shape and size of all supramolecular dendritic triangles were investigated with PM6 semiempirical molecular orbital methods.
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