Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 77, Issue 9, Pages 4271-4277Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo202663n
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Funding
- National Science Foundation of China [21072131]
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A novel and moderate synthesis of 2,5-disubstituted oxazoles and oxazolines involving ruthenium(II) porphyrin copper chloride catalyzed cyclization was developed. These reactions using readily available benzene carboxylic acids and phenylethenes or phenylacetylenes are performed under mild conditions. The reactions proceed in series, giving rise to the formation of an intermolecular C-N bond and an intramolecular C-O bond, which yield oxazole or oxazoline derivatives simultaneously.
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