Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 78, Issue 5, Pages 2046-2050Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo3020825
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Funding
- National Institutes of Health [GM095666]
- NSF [CHE-1048642]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1048642] Funding Source: National Science Foundation
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We describe the anti-Markovnikov hydrothiolation of olefins using visible-light-absorbing transition metal photocatalysts. The key thiyl radical intermediates are generated upon quenching of photoexcited Ru*(bpz)(3)(2) with a variety of thiols. The adducts of a wide variety of olefins and thiols are formed in excellent yield (73-99%).
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