4.7 Article

Ir-Catalyzed Direct Borylation at the 4-Position of Pyrene

Journal

JOURNAL OF ORGANIC CHEMISTRY
Volume 77, Issue 16, Pages 7124-7128

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jo301293w

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Funding

  1. National Natural Science Foundation of China [20802026, 50803033]
  2. Royal Society
  3. BP
  4. Alexander von Humboldt Foundation
  5. EPSRC
  6. Royal Society of Chemistry

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The first direct borylation of a C-H bond at the 4-position of pyrene was achieved using [Ir(COD)Cl](2)/dtbpy as the catalyst precursor and B(2)pin(2) as the boron source. The position-related photophysical properties of pyrene derivatives are reported.

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