Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 77, Issue 6, Pages 2966-2970Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo202686p
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Funding
- National Institutes of Health [R01 GM035249]
- Neuroscience Medicinal Chemistry Department of Janssen Pharmaceutica
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Efficient Csp(3)-Csp(3) Suzuki couplings have been developed with loth potassium cyclopropyl- and alkoxymethyltrifluoroborates. Moderate to good yields have been achieved in the cross-coupling of potassium cyclopropyltrifluoroborate with benzyl chlorides possessing electron-donating or electron-withdrawing substituents. Benzyl chloride was also successfully cross-coupled to potassium alkoxymethyltrifluoroborates derived from primary, secondary, and tertiary alcohols.
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