Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 77, Issue 4, Pages 1798-1804Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo2023262
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Funding
- Special Fund for Agro-scientific Research in the Public Interest [201103007]
- National Key Technologies RD Program [2011BAE06B05]
- Shanghai Scientific Research Program [10XD1405200]
- National Basic Research Program of China [2010CB126103, 2012CB821600]
- National Natural Science Foundation of China [21032006]
- SIOC
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A selective palladium-catalyzed Suzuki-Miyaura coupling reaction of polyfluorophenyl oxazolines through ortho C-F activation is described. It was found that reactions with DPPF as the ligand occurred much faster than those with other ligands. A variety of arylboronic acids including challenging functionalized arylboronic acids such as enolizable ketones, aldehyde, cyano, ester, and trifluoromethyl groups were tolerated with the reaction conditions.
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