Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 77, Issue 11, Pages 5149-5154Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo300562j
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Funding
- FWO (Fund for Scientific Research-Flanders (Belgium))
- University of Leuven
- FWO
- China Scholarship Council
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A novel microwave-assisted approach for the one-pot Cu(I)-catalyzed A(3)-coupling/decarboxylative coupling (PA(2)-coupling) of a propiolic acid, an aldehyde, and an amine, resulting in the formation of diversely substituted 1,4-diamino-2-butynes, is described. It is noteworthy that this new multicomponent coupling provides an efficient access to introduce alkyl and aryl group at the 1,4-position of the 1,4-diamino-2-butynes.
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