Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 77, Issue 12, Pages 5434-5438Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo300724m
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Funding
- CONACyT (Mexico) [129572]
- Gobierno Vasco [IT339-10, S-PE10UN65, S-PE11UN064]
- CONACyT
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The role of the amino group twisting ability in the BODIPY photophysics for nonsterically hindered and constrained molecular structures was studied. When a coplanar disposition of the amino and the BODIPY core is feasible, a hemicyanine-like delocalized pi-system gives rise to novel blue and efficient BODIPY laser dyes. The key role of such rotamer is confirmed by newly synthesized derivatives where the amino and the BODIPY core are electronically decoupled by steric repulsions.
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