Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 77, Issue 24, Pages 11339-11344Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo302125h
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Funding
- National Natural Science Foundation of China [21272117, 20972068]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
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A facile ortho-acylation of acetanilides by a Pd-catalyzed oxidative C-H activation was developed in which low toxic, stable, and commercially available toluene derivatives were first used as acylation reagents by a tandem reaction to form o-acylacetanilides with moderate to good yields. Inexpensive, safe, and environmentally benign TBHP was proved to be an effective oxidant for these transformations.
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