4.7 Article

Study on Metal-Induced Reactions of α-Diazocarbonyl Glucosides

Journal

JOURNAL OF ORGANIC CHEMISTRY
Volume 77, Issue 20, Pages 8888-8895

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jo300986c

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Funding

  1. Universite Pierre et Marie Curie-Paris 6 (UPMC)
  2. French Embassy in China

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Conversions of diazocarbonyl carbohydrate compounds catalyzed by a series of rhodium and copper catalysts in conventional heating or microwave conditions were investigated. C-H insertion product was obtained in the presence of Rh-2(OAc)(4). Intermolecular reactions rather than intramolecular reactions occurred in the presence of copper catalysts.

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