Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 77, Issue 5, Pages 2513-2518Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo202357s
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Funding
- Priority Research Centers Program [NRF-2011-0031392]
- Basic Science Research Program [NRF-2011-0002654]
- Midcareer Researcher Program [NRF-2011-0029186]
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Total synthesis of (+)-ambuic acid has been accomplished from the readily available stereocontrolled Diels-Alder adduct of cyclopentadiene and iodo-1,4-benzoquinone monoketal through an efficient series of steps. A new method for the highly commendable synthesis of alpha-brominated Diels-Alder adduct is described.
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