Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 77, Issue 8, Pages 3700-3703Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo300437t
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Funding
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0840521] Funding Source: National Science Foundation
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The ligands associated with various Pd catalysts play a crucial role in determining the stereochemistry of cross-couplings between boronic acids and Z-alkenyl halides. A ligand on palladium has been found that leads to the desired products under mild conditions and in high yields that, in most cases, retain their Z-olefin geometry.
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