Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 77, Issue 9, Pages 4491-4495Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo300519g
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- Deutsche Forschungsgemeinschaft [SFB 623]
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The first total synthesis of the polyketide apiosporic acid is presented. Key steps are a Julia-Kocienski olefination, a Suzuki-Miyaura cross-coupling, and an intramolecular Diels-Alder reaction. The absolute configuration of the natural product was determined.
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