Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 77, Issue 8, Pages 4167-4170Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo300374v
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Funding
- NSFC [21072085, 20921120404, 21102061, 20972059]
- National Basic Research Program of China (973 program) [2010CB833200]
- MOE
- fundamental research funds for the central universities [lzujbky-2012-86]
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A novel palladium-catalyzed cascade allylic amination/intramolecular hydroamination/isomerization process of protected enynol 1 and primary amine 2 has been explored, which constructs the important 1,2,5-trisubstituted pyrroles. This transformation offers an alternative synthetic methodology capable of generating substituted pyrroles in a straightforward way.
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