Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 77, Issue 10, Pages 4821-4825Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo300236u
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Funding
- CRI [2012-0001245]
- National Research Foundation of Korea (NRF)
- Korea government (MEST) [2009-0087013]
- Brain Korea 21 Program
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Indium tri(isopropoxide)-catalyzed Meerwein-Ponndorf-Verley reduction of aliphatic and aromatic aldehydes in 2-propanol gave selectively the corresponding primary alcohols in good to excellent yields at room temperature. A wide range of functional groups including alkene, ether; ketone, ester, nitrile, and nitro were tolerated under the optimum reaction conditions. Chemoselective reductions were also achieved not only between aromatic aldehyde, aromatic ketone, and epoxide but also between aliphatic aldehyde and alkene.
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