Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 77, Issue 18, Pages 8355-8361Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo301416s
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Funding
- National Basic Research Program of China [2009CB825300]
- National Natural Science Foundation of China [21272232]
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FeCl3 center dot 6H(2)O-catalyzed efficient C3-alkenylation of indoles was realized through the condensation of aldehydes and indole derivatives in the presence of 2 equiv of ethanol at ambient temperature, forming 3-vinylindoles in up to 93% yields. Ethanol promoted formation of the desired products. An obvious solvent effect was observed, and bisindoles were identified as the reaction intermediates.
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