Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 77, Issue 15, Pages 6473-6479Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo3010183
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Funding
- MIUR, Rome (FIRB-Futuro in Ricerca 2008 Project) [RBFR08J78Q]
- CINECA Supercomputer Center
- ISCRA COMPDHT [HP10CZEHG6]
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2-Substituted benzo[b]furans were synthesized by a one-step metal-free photochemical reaction between 2-chlorophenol derivatives and terminal alkynes by tandem formation of an aryl-C and a C-O bond via an aryl cation intermediate. The mild conditions and the application to chlorophenols rather of the more expensive bromo or iodo analogues makes this procedure environmentally convenient.
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