Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 76, Issue 15, Pages 5915-5923Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo201042c
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Funding
- NIH/NIGMS [MERS-RISE GM60655]
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The synthesis of 3,4,5-trisubstituted pyrazoles via a tandem catalytic cross-coupling/electrocydization of enol triflates and diazoacetates is presented. The initial scope of this methodology is demonstrated on a range of differentially substituted acyclic and cyclic enol triflates as well as an elaborated set of diazoacetates to provide the corresponding pyrazoles with a high degree of structural complexity.
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