4.7 Article

Pd-Diimine: A Highly Selective Catalyst System for the Base-Free Oxidative Heck Reaction

Journal

JOURNAL OF ORGANIC CHEMISTRY
Volume 76, Issue 9, Pages 3498-3501

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jo101942f

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Funding

  1. Abbott Healthcare Products B.V.

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Pd(OAc)(2)/3 is an efficient catalyst system for the base-free oxidative Heck reaction that outperforms the currently available catalysts for the more challenging substrates studied. The catalyst system is highly selective, and works at room temperature with dioxygen as the oxidant.

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