Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 76, Issue 19, Pages 8049-8052Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo2012412
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Funding
- Japan Society for the Promotion of Science [22245007, 22685006]
- Japan Science and Technology Agency [AS2211281D]
- Nissan Science Foundation
- Grants-in-Aid for Scientific Research [22685006, 22245007] Funding Source: KAKEN
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Oxosumanenes were synthesized through benzylic oxidation. The electronic and redox properties were revealed to exhibit the expanded pi-conjugation compared to sumanene. Single-crystal X-ray analysis of monooxosumanene showed columnar pi-stacking in a concave-convex fashion. Stereoselective trimethylation of the trioxo derivative was performed via 1,2-addition to the carbonyl groups.
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