Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 76, Issue 19, Pages 8036-8041Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo201196a
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Funding
- National Natural Science Foundation of China [20802015, 21072040, 21071040]
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An efficient Pd-catalyzed Heck reaction of aryl chlorides with olefins under mild conditions is described. High yields of products were achieved with n-Bu(4)N(+)OAc(-) as base. Significantly, the temperature of the Heck reaction of diverse nonactivated aryl chlorides can be lowered to 80 degrees C. The new reaction system can also tolerate a wider range of olefins.
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