4.7 Article

Cobalt-Catalyzed Preparation of Arylindium Reagents from Aryl and Heteroaryl Bromides

Journal

JOURNAL OF ORGANIC CHEMISTRY
Volume 76, Issue 18, Pages 7563-7568

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/jo201174r

Keywords

-

Funding

  1. Singapore National Research Foundation [NRF-RF2009-05]
  2. Nanyang Technological University

Ask authors/readers for more resources

A cobalt bathophenanthroline catalyst has been developed for the direct preparation of a variety of arylindium reagents from the corresponding aryl and heteroaryl bromides in the presence of indium metal and lithium chloride. The thus-formed arylindium reagents undergo efficient palladium-catalyzed cross-coupling reactions with aryl iodides, tolerating various functional groups including hydroxy and free amino groups.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.7
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available